KNOPPIX is a bootable CD with a collection of GNU/Linux software, automatic hardware detection, and support for many graphics cards, sound cards, SCSI devices, and other peripherals. It can be used as a Linux demo, educational CD, rescue system, etc. It is not necessary to install anything on a hard disk due to on-the-fly decompression.
GNUSTEP Live CD contains a lot of software for GNUstep, a free implementation of the OPENSTEP framework (which is also directly used in Mac OS X as Cocoa). It includes excellent applications for RAD (GORM and ProjectCenter). The CD is available for i486, AMD64, Apple Mac PowerPC, and Sun UltraSPARC computers.