Grml is a live system (live CD) based on Debian. It includes a collection of GNU/Linux software especially for system administrators and users of texttools. It provides automatic hardware detection and its default shell is the zsh. You can use it e.g. as a rescue system, for analyzing systems/networks, or as a working environment. It is not necessary to install anything to a hard disk; you don't even need a hard disk to run it. Due to on-the-fly decompression, it includes more than 2 GB of software and documentation on the CD.
iloog is a Gentoo-based live CD targeted mainly at students and scientists. It features UnionFS filesystem support that enables you to write everywhere on the LiveCD and install extra packages, a graphical X environment through the Fluxbox window manager, many programming editors and IDEs, and a plethora of scientific applications, including Octave, Namd, Merlin, and full (La)TeX support.